Both aldehyde and ketone contain
Active group of aldehyde is and ketone's active group is
You can identify a ketone from acidic potassium permanganate. Purple colour of acidic potassium permanganate is not changed because there is no reaction between ketone and acidic potassium permanganate.
You can identify the aldehyde from acidic potassium permanganate. Purple colour of acidic potassium permanganate is changed to colourless because aldehyde is oxidized by acidic potassium permanganate.
Due to different active groups, aldehyde and ketone indicate different reactions for same reagent. But sometimes they show same changes (like colour changes) to some reagents.
The best way to identify aldehyde from ketone is checking the oxidizing of aldehyde or ketone compound. Observe the colour change which is related to the aldehyde compound. The colour change is occurred in aldehyde sample.
Aldehyde are oxidized to carboxylic acids by both strong and mild oxidizing agents.
Aldehyde are oxidized to alcohols by strong oxidizing agents and their colour changes will notify strong oxidizing agents are being reduced.
Tollen's reagent is prepared by dissolving silver hydroxide, the white precipitate in ammonia solution.
When aldehyde is oxidized to carboxylic acid, Ag+ ion is reduced to Ag which is deposited in the bottom of the test tube. Deposited silver is shown as a silver mirror.
But we cannot identify formic acid from aldehyde from tollen's reagent because formic acid is oxidized to carbon dioxide. So both aldehyde and formic acid reacts with tollen's reagent and we cannot observe a different thing in two cases.
How do you identify aldehyde from formic acid?
Formic acid is the simplest carboxylic acid compound. We can use different characteristics of carboxylic acids and aldehydes to identify aldehyde from formic acid.
From this method, we try to produce primary and secondary alcohols and then check their differences to identify aldehyde and ketone.
As lucas' reagent, we use anhydrous zinc chloride and concentrated hydrochloride acid (ZnCl2/HCl). This reagent is much suitable for, identify primary alcohols and secondary alcohols.
But, from good observation, you can identify primary alcohols and secondary alcohols too.
Below table shows some experiments can be done to identify aldehyde and ketone
|Brady's Reagent||Orange colour precipitate||Orange colour precipitate|
|NH2OH||Colourless precipitate, does not dissolve in water||Colourless precipitate, does not dissolve in water|
|Acidic KMnO4||Purple colour is changed to light pink or colourless||No difference|
|Acidic K2Cr2O7||Orange colour is changed to green||No difference|
|Tollen's Reagent||Silver deposits, (silver mirror)||No reaction|
|Fehlinghs's Reagent (blue colour)||Aliphatic aldehydes are oxidized. A brick red colour, Cu2O forms.||No reaction|
There are so many compounds which can react with aldehyde and ketone.
Questions for you
Decide whether following statements are true or false?
Correct. Oxidation of primary alcohols and secondary alcohols give aldehydes and ketones respectively.
False. You cannot do this in single step. Then how it is possible? have to follow several reactions or sometimes it is completely impossible to do.